Thermal Properties of Matter
PromiseSeparate expansion, heat balance and conduction in 15 seconds; one conservation or Fourier statement plus unit discipline finishes the stem.
01. Linear, area and volume expansion: ΔL=αLΔT, ΔA=2αAΔT, ΔV=γVΔT with γ≈3α for isotropic solids. Apparent expansion of liquid in a vessel uses γ_liquid−γ_vessel.
02. Calorimetry conserves energy when losses are neglected: heat lost = heat gained, including mL for phase change at fixed temperature.
03. Conduction (1D steady): H=dQ/dt=KA(ΔT)/x. Series and parallel slabs combine like thermal resistances R=x/(KA).
How Advanced asks this
- Rod/clock/gap expansion; bimetallic bend direction
- Liquid-in-glass apparent expansion; overflow volume
- Mixture calorimetry with or without latent heat; final phase
- Steady heat current through composite slab; interface temperature
- Newton cooling: time to cool between two temperatures
- Mixed statements on good/bad conductors, emissivity cues, or expansion coefficients
Traps that leak marks
- Using γ=2α for volume expansion
- Ignoring vessel expansion for liquid overflow
- Assuming final T without checking phase completion
- Adding K instead of combining thermal resistances
- Using average rate instead of Newton’s logarithmic law
- Importing Stefan–Boltzmann into a pure conduction numerical
- Using γ=2α for volume expansion
- Ignoring vessel expansion for liquid overflow
- Assuming final T without checking phase completion
Must cover (this topic)
- Thermal expansion; calorimetry; latent heat; conduction (1D); convection/radiation ideas; Newton’s cooling
60–90s process
- 0–15s — Classify: solid/liquid expansion, calorimetry/phase change, 1D conduction network, or Newton cooling.
- 15–35s — Write ΔL/ΔV formulas, ΣQ=0 heat ledger, H=KAΔT/x (or thermal R), or ln cooling integral.
- 35–75s — Track which body expands, whether phase change completes, and series vs parallel for slabs.
- 75–90s — Check final T between extremes, energy sign (lost vs gained), and that radiation Stefan law was not forced unless needed.
Methods that change the score
Expansion laws and phase-feasible calorimetry keep thermal numericals physical.
Method 01 · Who expands?
Gap, ring-on-rod and clock stems hinge on which length grows.
Do this: Apply α or γ to the object whose dimension is constrained or measured—not blindly to every length in the figure.
Method 02 · Phase-aware heat ledger
Prevents illegal ‘final T below 0 °C with leftover ice’ style mistakes.
Do this: Bring each substance to the transition T, pay mL, then continue with mcΔT; stop if latent heat budget runs out.
Method 03 · Thermal circuit
Interface temperatures drop out cleanly like voltage dividers.
Do this: Replace each slab by R=x/(KA); series add R, parallel add 1/R; H=ΔT_total/R_eq.
Method 04 · Newton log interval
Avoids treating cooling rate as constant ΔT/Δt.
Do this: Integrate dθ/(θ−θ₀)=−k dt between the two temperatures given.
Quick formulas
- Linear / volume expansion: ΔL=αLΔT; ΔV=γVΔT; γ≈3α (isotropic) — Solids and temperature change
- Apparent expansion: γ_app=γ_liq−γ_vessel — Liquid expanding in a container
- Heat capacity: Q=mcΔT; Q=mL (phase change) — Calorimetry without chemical reaction
- Energy balance: ΣQ_lost+ΣQ_gained=0 (ideal calorimeter) — Mixture and phase problems
- Conduction: H=KA(T_hot−T_cold)/x — Steady 1D slab
- Thermal resistance: R=x/(KA); H=ΔT/R_eq — Series/parallel composites
- Newton cooling: dθ/dt=−k(θ−θ₀); ln[(θ₁−θ₀)/(θ₂−θ₀)]=kt — Cooling/heating toward ambient
Common question families
Linear/area/volume expansion
Looks like: Gap closing, apparent expansion, or bimetallic
Fast model: ΔL=LαΔT; γ≈3α; apparent = true − vessel.
Calorimetry and latent heat
Looks like: Mixture to equilibrium temperature/phase
Fast model: ΣQ=0 with mcΔT and mL terms; test phase feasibility.
Heat capacity of solids/liquids
Looks like: Specific heat from mixing or electrical heating
Fast model: Q = mcΔT = VIt or power×time when heated electrically.
Thermal stress
Looks like: Rod fixed between walls heated
Fast model: If expansion prevented, stress = Y α ΔT.
Sample preview · Linear/area/volume expansion
A steel rod (α=10⁻⁵ /°C) of length 1 m is heated by 100 °C. Find free expansion.
Answer: 1 mm
Free expansion ignores stress.