Physics notes / Thermal Physics

Thermal Physics · 100% marks notes

Thermal full marks = label the process or heat path in ≤15s, then run expansion/calorimetry, kinetic averages, first-law cycle, or radiation templates inside 60–90 seconds.

Goal Bank ~10–14 /100 Phys (~full Thermal share)Weight ~12% of Physics tags (2020–2026)Speed 60–90sShare 11.5%Trend Stable
Thermal in Advanced is expansion/calorimetry/conduction, kinetic theory, thermodynamics cycles, and radiation. 100% means path before w/q, phase-feasible calorimetry, and kelvin before T⁴ — never start from a random formula. Thermal full marks are process labels + correct state variables.
Topic-wise on this page

Thermal Physics · chapter details

Same content as each topic page — brief, paper asks, methods, formulas, and families — so you can study here first, then open a full topic only when you need samples or trends.

01 · Calorimetry and expansion numericals with a steady conduction lane

Thermal Properties of Matter

Full topic page →

PromiseSeparate expansion, heat balance and conduction in 15 seconds; one conservation or Fourier statement plus unit discipline finishes the stem.

Thermal properties is macroscopic bookkeeping: lengths/volumes change with T, heat reshuffles with c and L, and 1D conduction moves energy down a gradient. Do not drag full Carnot machinery into a calorimetry stem. Thermal template: expansion / calorimetry / conduction / cooling → write the balance → verify final phase or steady-state assumptions.

01. Linear, area and volume expansion: ΔL=αLΔT, ΔA=2αAΔT, ΔV=γVΔT with γ≈3α for isotropic solids. Apparent expansion of liquid in a vessel uses γ_liquid−γ_vessel.

02. Calorimetry conserves energy when losses are neglected: heat lost = heat gained, including mL for phase change at fixed temperature.

03. Conduction (1D steady): H=dQ/dt=KA(ΔT)/x. Series and parallel slabs combine like thermal resistances R=x/(KA).

How Advanced asks this

  • Rod/clock/gap expansion; bimetallic bend direction
  • Liquid-in-glass apparent expansion; overflow volume
  • Mixture calorimetry with or without latent heat; final phase
  • Steady heat current through composite slab; interface temperature
  • Newton cooling: time to cool between two temperatures
  • Mixed statements on good/bad conductors, emissivity cues, or expansion coefficients

Traps that leak marks

  • Using γ=2α for volume expansion
  • Ignoring vessel expansion for liquid overflow
  • Assuming final T without checking phase completion
  • Adding K instead of combining thermal resistances
  • Using average rate instead of Newton’s logarithmic law
  • Importing Stefan–Boltzmann into a pure conduction numerical
  • Using γ=2α for volume expansion
  • Ignoring vessel expansion for liquid overflow
  • Assuming final T without checking phase completion

Must cover (this topic)

  • Thermal expansion; calorimetry; latent heat; conduction (1D); convection/radiation ideas; Newton’s cooling

60–90s process

  1. 0–15s — Classify: solid/liquid expansion, calorimetry/phase change, 1D conduction network, or Newton cooling.
  2. 15–35s — Write ΔL/ΔV formulas, ΣQ=0 heat ledger, H=KAΔT/x (or thermal R), or ln cooling integral.
  3. 35–75s — Track which body expands, whether phase change completes, and series vs parallel for slabs.
  4. 75–90s — Check final T between extremes, energy sign (lost vs gained), and that radiation Stefan law was not forced unless needed.

Methods that change the score

Expansion laws and phase-feasible calorimetry keep thermal numericals physical.

Method 01 · Who expands?

Gap, ring-on-rod and clock stems hinge on which length grows.

Do this: Apply α or γ to the object whose dimension is constrained or measured—not blindly to every length in the figure.

Method 02 · Phase-aware heat ledger

Prevents illegal ‘final T below 0 °C with leftover ice’ style mistakes.

Do this: Bring each substance to the transition T, pay mL, then continue with mcΔT; stop if latent heat budget runs out.

Method 03 · Thermal circuit

Interface temperatures drop out cleanly like voltage dividers.

Do this: Replace each slab by R=x/(KA); series add R, parallel add 1/R; H=ΔT_total/R_eq.

Method 04 · Newton log interval

Avoids treating cooling rate as constant ΔT/Δt.

Do this: Integrate dθ/(θ−θ₀)=−k dt between the two temperatures given.

Quick formulas

  • Linear / volume expansion: ΔL=αLΔT; ΔV=γVΔT; γ≈3α (isotropic) — Solids and temperature change
  • Apparent expansion: γ_app=γ_liq−γ_vessel — Liquid expanding in a container
  • Heat capacity: Q=mcΔT; Q=mL (phase change) — Calorimetry without chemical reaction
  • Energy balance: ΣQ_lost+ΣQ_gained=0 (ideal calorimeter) — Mixture and phase problems
  • Conduction: H=KA(T_hot−T_cold)/x — Steady 1D slab
  • Thermal resistance: R=x/(KA); H=ΔT/R_eq — Series/parallel composites
  • Newton cooling: dθ/dt=−k(θ−θ₀); ln[(θ₁−θ₀)/(θ₂−θ₀)]=kt — Cooling/heating toward ambient

Common question families

Linear/area/volume expansion

Looks like: Gap closing, apparent expansion, or bimetallic

Fast model: ΔL=LαΔT; γ≈3α; apparent = true − vessel.

Calorimetry and latent heat

Looks like: Mixture to equilibrium temperature/phase

Fast model: ΣQ=0 with mcΔT and mL terms; test phase feasibility.

Heat capacity of solids/liquids

Looks like: Specific heat from mixing or electrical heating

Fast model: Q = mcΔT = VIt or power×time when heated electrically.

Thermal stress

Looks like: Rod fixed between walls heated

Fast model: If expansion prevented, stress = Y α ΔT.

Sample preview · Linear/area/volume expansion

A steel rod (α=10⁻⁵ /°C) of length 1 m is heated by 100 °C. Find free expansion.

Answer: 1 mm

Free expansion ignores stress.

More samples on full topic page →

Open full Thermal props notes (samples · trends · joins) →

02 · Ideal-gas micro↔macro bridge; C_V/C_P and adiabatic indices are frequent

Kinetic Theory of Gases

Full topic page →

PromiseLock degrees of freedom and process type (isothermal vs adiabatic) early; then RMS/pressure relations and C_P−C_V=R finish most numericals.

Kinetic theory connects P=⅓ρv_rms² to macroscopic ideal-gas laws and heat capacities. Advanced tests whether you know what stays constant on a path and how γ enters sound speed and adiabatic bulk modulus. KTG template: ideal assumptions → f and γ → microscopic or process ask → SI units for M and R. Mixture ⇒ ⟨C_V⟩ then γ.

01. Ideal gas: PV=nRT; microscopic pressure P=⅓ρv_rms² with ½m v_rms²=(3/2)k_BT for translational motion in 3D.

02. Equipartition: each active quadratic degree of freedom contributes ½k_BT per molecule. Monatomic f=3; diatomic f=5 (near room T, rotation on).

03. C_V=fR/2 per mole, C_P=C_V+R, γ=C_P/C_V. Isothermal: T fixed, U fixed for ideal gas. Adiabatic: Q=0, TV^{γ−1}=const, PV^γ=const.

How Advanced asks this

  • v_rms, v_avg, v_mp comparison or ratio after T or M change
  • Pressure/KE from kinetic interpretation; mean KE and total U
  • C_V, C_P, γ for mono/dia/mixture; heat at constant P or V
  • Isothermal vs adiabatic curves; work and ΔU on a path
  • Bulk modulus of gas / speed of sound link
  • Mixture of gases: mean molar mass, effective γ or C_V

Traps that leak marks

  • Using γ=5/3 for diatomic air
  • Averaging γ of mixture instead of C_V
  • Setting ΔU≠0 for isothermal ideal gas
  • Using isothermal B for sound speed
  • Putting M in g mol⁻¹ into SI speed formulas
  • Confusing v_rms with most probable speed
  • Using γ=5/3 for diatomic air
  • Averaging γ of a mixture instead of C_V
  • Putting M in g mol⁻¹ into SI speed formulas

Must cover (this topic)

  • Cv/Cp mono & diatomic

60–90s process

  1. 0–15s — Classify: speed/KE kinetic, heat capacity/γ, isothermal path, adiabatic path, or bulk modulus/sound.
  2. 15–35s — Write f → C_V, C_P, γ; or P=⅓ρv_rms²; or process constraints (T const vs PV^γ).
  3. 35–75s — Use moles consistently; for mixtures weight C_V by mole fraction; keep R units matched to energy.
  4. 75–90s — Check mono vs dia f, whether U depends only on T, and isothermal B=P vs adiabatic B=γP.

Methods that change the score

Speed definitions and f→C_v→γ convert kinetic theory into ratio algebra.

Method 01 · f → γ pipeline

Prevents using γ=5/3 on a diatomic adiabatic stem.

Do this: Read mono/dia/mixture → f → C_V → C_P → γ before any process formula.

Method 02 · U from T only

Separates state functions from path functions early.

Do this: For ideal gas compute ΔU=nC_VΔT regardless of path shape; path affects Q and W.

Method 03 · Ratio before constants

Fast MCQ ratios without calculator thrash.

Do this: Cancel R,M when comparing speeds or P after T change.

Method 04 · Modulus matches process

Explains why Newton’s old √(P/ρ) underestimates sound speed.

Do this: Sound/rapid compression → adiabatic B=γP; slow isothermal → B=P.

Quick formulas

  • Ideal gas: PV=nRT=Nk_BT — Macroscopic state
  • Kinetic pressure: P=⅓ρ v_rms²; v_rms=√(3RT/M)=√(3P/ρ) — Ideal-gas kinetic link
  • Translational KE: ½m v_rms²=(3/2)k_BT; U_trans=(3/2)nRT — 3D translation
  • Heat capacities: C_V=fR/2; C_P=C_V+R; γ=1+2/f — Ideal gas, active f
  • Speeds: v_mp=√(2RT/M); v_avg=√(8RT/πM); v_rms=√(3RT/M) — Maxwell distribution markers
  • Adiabatic: PV^γ=const; TV^{γ−1}=const; TP^{(1−γ)/γ}=const — Reversible adiabatic ideal gas
  • Bulk modulus: B_iso=P; B_ad=γP — Gas compressibility / sound
  • Internal energy: ΔU=n C_V ΔT (ideal gas, any path) — State function U(T) for ideal gas

Common question families

Ideal-gas microscopic averages

Looks like: v_rms, v_avg, pressure from molecular speeds

Fast model: P=(1/3)ρv_rms²; v_rms=√(3RT/M).

Degrees of freedom and C_v, C_p

Looks like: Mono/di/polyatomic heat capacities

Fast model: C_v = (f/2)R; C_p = C_v+R; γ=1+2/f.

Mixture of ideal gases

Looks like: Mean molar mass, γ_mix, or partial pressures

Fast model: Use mole-weighted averages for M and C_v.

Mean free path / collision basics

Looks like: λ or collision frequency order-of-magnitude

Fast model: λ ∼ 1/(√2 π d² n) with n=N/V.

Sample preview · Ideal-gas microscopic averages

Find the ratio v_rms(H₂)/v_rms(O₂) at the same temperature.

Answer: 4

Lighter gases have larger rms speeds at equal T.

More samples on full topic page →

Open full KTG notes (samples · trends · joins) →

03 · First-law bookkeeping and Carnot limits — Advanced often joins with KTG γ and P–V cycles

Thermodynamics

Full topic page →

PromiseFix the sign convention and process type in 15 seconds; First-law ledger plus Carnot bound controls almost every Advanced thermo stem, including multi-process cycles.

Thermodynamics here is heat–work–internal energy accounting for ideal gases, plus Second-law limits. Papers punish silent sign flips more than missing γ. Recent Advanced styles mix process identification on P–V diagrams with Carnot bounds and irreversible vs reversible statements. State every convention before substituting. Thermo template: convention → process list → ΔU from state → Q,W from constraints → cycle audit. Kelvin for any T ratio.

01. Heat and work are path functions; U is a state function. First law (common Physics convention): ΔU=Q−W with W=work done by the system, or check the paper’s stated form ΔU=Q+W if W is on the system—pick one and never mix mid-solution.

02. For ideal gases, ΔU=nC_VΔT on every path. Isothermal ⇒ ΔU=0; isochoric ⇒ W=0 (P dV); isobaric ⇒ W=PΔV; adiabatic ⇒ Q=0.

03. Second law: heat engines need two reservoirs; Carnot efficiency η=1−T_C/T_H (kelvin) is the upper bound for reversible engines between those temperatures.

How Advanced asks this

  • P–V diagram: identify process, compute Q, W, ΔU for a cycle or path
  • Ideal-gas First-law numerical with mixed processes
  • Heat engine / refrigerator: η, COP, Carnot limit comparison
  • Reversible vs irreversible adiabatic or isothermal statements
  • Equivalence of heat and work; mechanical equivalent contexts
  • Multi-correct on what is state function vs path function
  • Join with KTG: γ enters adiabatic work and Carnot only through T, not γ itself

Traps that leak marks

  • Mixing First-law sign conventions mid-problem
  • Using °C in Carnot formula
  • Counting heat rejected as part of Q_H
  • Applying PV^γ to irreversible adiabatics
  • Claiming ΔU depends on path for ideal gas
  • Confusing engine η with refrigerator COP
  • Mixing First-law signs mid-problem
  • Using °C inside Carnot efficiency
  • Applying PV^γ to irreversible adiabatics

Must cover (this topic)

  • First law for ideal-gas processes
  • Carnot efficiency

60–90s process

  1. 0–15s — Write sign convention explicitly; classify process(es) and whether a cycle (ΔU=0).
  2. 15–35s — For each leg: ΔU=nC_VΔT; then Q and W from process constraints; for engines use Q_H, Q_C, W.
  3. 35–75s — Sum cycle quantities; apply Carnot bound if efficiency is compared to T_C, T_H.
  4. 75–90s — Check kelvin temperatures, ΔU=0 on cycle, and that irreversible claims were not given reversible formulas blindly.

Methods that change the score

Path labels fix w and q; state functions fix ΔU — Advanced cycles punish silent sign flips.

Method 01 · Convention stamp

Eliminates the #1 Advanced thermo arithmetic error.

Do this: Write ‘W by’ or ‘W on’ at the top of the rough sheet before any number.

Method 02 · Leg table

Cycles become addition, not narrative.

Do this: For each process column: type | ΔT | ΔU | W | Q.

Method 03 · Carnot ceiling

Instant multi-correct filter on impossible engines.

Do this: Before trusting a claimed η, compute 1−T_C/T_H and reject anything larger.

Method 04 · State vs path split

Blocks irreversible-process traps.

Do this: Compute ΔU from endpoints only; never infer Q from ΔU alone without the path.

Quick formulas

  • First law: ΔU=Q−W (W by system) — or ΔU=Q+W (W on system); lock one — Every thermo energy balance
  • Ideal gas U: ΔU=n C_V ΔT (any path) — Ideal gas
  • Work (quasi-static): W_by=∫P dV; isobaric PΔV; isothermal nRT ln(V₂/V₁) — Ideal-gas paths
  • Adiabatic work: W_by=(nRΔT)/(1−γ)=−ΔU (Q=0) — Reversible adiabatic ideal gas
  • Engine efficiency: η=W/Q_H=1−|Q_C|/Q_H — Heat engine
  • Carnot: η_C=1−T_C/T_H (T in kelvin) — Reversible engine between two reservoirs
  • Refrigerator COP: COP=Q_C/W=Q_C/(Q_H−Q_C) — Fridge/heat pump definitions differ—read ask
  • Cycle: ΔU_cycle=0 ⇒ Q_net=W_net (with consistent signs) — Closed cycles

Common question families

First-law process accounting

Looks like: Isochoric/isobaric/isothermal/adiabatic/irreversible

Fast model: Label path; then ΔU=q+w with paper’s sign convention.

PV diagram cycle work

Looks like: Closed loop; efficiency or net work

Fast model: W_net = area; for ideal gas use process formulas on each leg.

Adiabatic and polytropic relations

Looks like: TV^{γ−1}, PV^γ, or polytropic n

Fast model: Use the matching invariant for reversible adiabatic ideal gas.

Carnot and second-law limits

Looks like: η_Carnot, refrigerator COP, or irreversibility

Fast model: η≤1−T_C/T_H; equality only for Carnot.

Sample preview · First-law process accounting

One mole ideal gas is heated isochorically so ΔT=10 K. Take C_v=1.5R. Find ΔU.

Answer: 15R

Isochoric ΔU still follows C_vΔT.

More samples on full topic page →

Open full Thermo notes (samples · trends · joins) →

04 · Stefan/Wien/Kirchhoff numericals and net-rate patterns; deepen exam radiation habits

Heat Transfer & Radiation

Full topic page →

PromiseTreat radiation as power laws in T and e/a; Kirchhoff links e and a, Stefan gives net power, Wien shifts the spectrum—audit T⁴ and kelvin every time.

This topic sharpens radiation and heat-transfer exam patterns beyond the thermal-properties sketch: blackbody powers, Kirchhoff’s law, Wien displacement, Stefan–Boltzmann net exchange, and when conduction/convection language is only qualitative scaffolding. Radiation template: kelvin → emitted vs net → e/a via Kirchhoff → energy balance for cooling. Wien only for λ_max.

01. A blackbody absorbs all incident radiation (a=1) and is the ideal emitter. Absorptive power a and emissive power e are linked by Kirchhoff: e/a is universal for a given λ,T for bodies in equilibrium with radiation—good absorbers are good emitters.

02. Stefan–Boltzmann: power radiated E=σA T⁴ for a blackbody; for grey body eσA T⁴ with emissivity e≤1. Net power when surrounded by T₀ is eσA(T⁴−T₀⁴) (same e on absorb/emit if Kirchhoff applies).

03. Wien: λ_max T=b (displacement). Hotter bodies peak at shorter wavelength; total power still follows T⁴.

How Advanced asks this

  • Net radiation rate between body and enclosure; time to cool via mc dT/dt
  • λ_max comparison via Wien; colour/temperature ordering
  • Kirchhoff statements: absorptive vs emissive power, blackbody limits
  • Ratio of powers at two temperatures; e unknown cancels
  • Sphere cooling / same mass different shapes: area dependence
  • Mixed conduction–radiation qualitative ranking (which dominates)

Traps that leak marks

  • Leaving temperature in °C inside T⁴
  • Using P=σAT⁴ when net exchange with T₀ is required
  • Applying Wien’s constant to total power
  • Assuming polished surfaces radiate as blackbodies
  • Confusing emissive power with absorptive power without Kirchhoff
  • Using Newton cooling linear law when the stem is pure T⁴ radiation
  • Leaving temperature in °C inside T⁴
  • Using emitted-only power when net exchange is required
  • Applying Wien’s constant to total power

Must cover (this topic)

  • Wien / Stefan / Kirchhoff radiation

60–90s process

  1. 0–15s — Classify: Stefan net power, Wien λ_max, Kirchhoff e–a, or cooling differential with radiation.
  2. 15–35s — Write P_net=eσA(T⁴−T₀⁴), λT=b, or e/a logic; convert all T to kelvin.
  3. 35–75s — Cancel σ,e,A in ratios; for cooling couple P_net to mc dT/dt when asked.
  4. 75–90s — Check T⁴ not T, blackbody e=1, and that Wien uses λ_max not arbitrary λ.

Methods that change the score

Thermal resistance networks and net T⁴ radiation replace vague heat-flow talk.

Method 01 · Kelvin-and-fourth audit

Most radiation numerical disasters are °C left in place or linear ΔT habits.

Do this: Convert °C→K before any T⁴; estimate whether T≪T₀ terms matter.

Method 02 · Ratio cancel

Leaves pure (T₁/T₂)⁴ or net (T⁴−T₀⁴) ratios.

Do this: For P₁/P₂ at two T, cancel e,σ,A when unchanged.

Method 03 · Kirchhoff filter

Statement options die without computing σ.

Do this: Translate colour/polish statements into high/low a and hence high/low e.

Method 04 · Area-to-energy couple

Same-volume shape comparisons become pure geometry.

Do this: When mass/c fixed, dT/dt∝−A(T⁴−T₀⁴); maximise A for faster radiative cooling.

Quick formulas

  • Stefan (black): P=σ A T⁴; σ=5.67×10⁻⁸ W m⁻² K⁻⁴ — Ideal emitter
  • Grey / net: P_net=e σ A (T⁴−T₀⁴) — Body in large enclosure at T₀
  • Kirchhoff: e_λ / a_λ = f(λ,T); good absorber ⇒ good emitter — Equilibrium radiation exchange
  • Wien: λ_max T=b ≈2.89×10⁻³ m·K — Spectral peak vs temperature
  • Emissive power: E=e E_black; a≤1, e≤1; black a=e=1 — Real surface comparison
  • Cooling link: mc dT/dt=−eσA(T⁴−T₀⁴) (radiation-dominated) — Rate of fall of temperature
  • Energy radiated: ΔU_rad=∫P_net dt — Finite-time radiation loss

Common question families

Conduction (1D steady)

Looks like: Slab, composite wall, or rate H=kAΔT/L

Fast model: Series thermal resistances add; parallel conductances add.

Newton’s law of cooling

Looks like: dT/dt ∝ (T−T₀); calorimeter cooling

Fast model: Integrate exponential approach to ambient.

Stefan / blackbody power

Looks like: Net power σA(T⁴−Tₛ⁴) or eσAT⁴

Fast model: Use net radiation when surroundings matter.

Wien displacement

Looks like: λ_max T = b; spectrum peak shift

Fast model: Apply Wien directly; higher T ⇒ shorter λ_max.

Sample preview · Conduction (1D steady)

A slab of thickness 2 cm, area 0.1 m² and k=0.2 W m⁻¹ K⁻¹ has faces at 100 °C and 0 °C. Find heat current.

Answer: 100 W

Steady conduction is a thermal Ohm’s law.

More samples on full topic page →

Open full Radiation notes (samples · trends · joins) →

Read first

How to use these notes for 100%

Point 01

Depth upgrade: Thermodynamics is process accounting (ΔU=Q−W with your sign convention locked). Cycles need state points before efficiency slogans.

Point 02

Radiation laws (Wien/Stefan) are families — identify which quantity is held fixed before writing proportions.

Speed system

60–90 second answer protocol

Use this on every stem — SC, MC, NUM, MATCH.

  1. 0

    0–15s — Name the family: Expansion / Calorimetry / Kinetic / First-law process / Cycle / Conduction / Radiation/Wien. Circle T units and what is asked (Q, W, ΔU, η, H, λ_max).

  2. 15

    15–35s — Stamp path (isochoric/isobaric/isothermal/adiabatic) or phase hypothesis; write governing relations only (ΔU=nC_vΔT, ΣQ=0, R=L/(kA), σAT⁴).

  3. 35

    35–75s — Plug carefully; for cycles fill a leg table and verify ΣΔU=0; for radiation convert °C→K before powers.

  4. 75

    75–90s — Sanity: sign convention, Carnot bound, phase feasibility, kelvin check. Bubble.

Transferable knowledge

Universal methods (all problem types)

Automate these — they apply across years and formats for this portion.

Method 01

Path label before w and q

Applies toIdeal-gas first-law numericals

The move

Name the process; ΔU=nC_vΔT always; then path rule for w; q from first law with the paper’s sign convention.

Why it saves time

Stops using isothermal w on isochoric stems.

Method 02

Phase-feasible calorimetry

Applies toIce/steam mixtures, latent heat

The move

Guess final phase; write ΣQ=0 with mcΔT and mL; reject roots outside the assumed range.

Why it saves time

Avoids long wrong algebra after an impossible T_f.

Method 03

Mole-weighted kinetic averages

Applies toMixtures, C_v, γ, partial pressures

The move

Average C_v (and M) by moles; never average γ linearly; Dalton for partial pressures.

Why it saves time

Mixture MC dies without expanding every molecule story.

Method 04

Cycle leg table

Applies toPV loops, engines, refrigerators

The move

List each process’s ΔU, W, Q; sum; η=W_net/Q_in only (heat absorbed).

Why it saves time

Prevents counting |Q_out| inside efficiency.

Method 05

Thermal resistance network

Applies toComposite slabs, steady conduction

The move

R=L/(kA); series add R; parallel add conductances; H=ΔT/R_eq.

Why it saves time

Turns layered-wall stems into circuit algebra.

Method 06

Kelvin before T⁴ / Wien

Applies toStefan, Newton cooling, λ_max T=b

The move

Convert temperatures; use net σA(T⁴−T₀⁴) when surroundings matter; keep Wien separate from Stefan.

Why it saves time

Celsius-in-T⁴ is the classic radiation trap.

Instant recall

Mental bank

Keep these cold — no derivation during the 60–90s window.

  • ΔL=LαΔT; γ≈3α; thermal stress ≈ YαΔT if fully constrained
  • Ideal gas: PV=nRT; ΔU=nC_vΔT
  • C_v=(f/2)R; C_p=C_v+R; γ=1+2/f
  • Isothermal reversible: w=−nRT ln(V₂/V₁) (paper sign)
  • Adiabatic: PV^γ, TV^{γ−1}; q=0
  • Carnot: η=1−T_C/T_H (kelvin)
  • v_rms=√(3RT/M); P=(1/3)ρ v_rms²
  • H=kAΔT/L; P_net=eσA(T⁴−T₀⁴); λ_max T=b
  • Lock sign convention for first law
  • Ideal-gas ΔU depends on T only
  • Carnot is a bound, not a default engine
Inside Thermal

Sub-portion playbooks

Each family has a trigger, template, and drill.

01 · Medium–High

Thermal Properties · Calorimetry · Conduction

45s triggerSee gap/α, mixture/latent, or composite slab → expansion law, ΣQ=0, or R network.

Template (write on rough)

  1. Expansion: free vs constrained; include vessel for liquids.
  2. Calorimetry: phase hypothesis → ΣQ=0 → feasibility check.
  3. Conduction: draw R=L/(kA); combine; H=ΔT/R.
  4. Electrical heating: VIt = mcΔT when relevant.

Must automate

  • Apparent expansion of liquid in vessel
  • Ice–water–steam heat accounting
  • Series slab interface temperature

Traps

  • Latent heat applied away from the phase-change temperature
  • Parallel slabs treated as series resistances

Drill

Daily: 1 calorimetry or expansion + 1 conduction stem

02 · Highest Thermal yield

Kinetic Theory · Thermodynamics

45s triggerSee v_rms/C_v or w/q/cycle → f→C_v or path label.

Template (write on rough)

  1. Kinetic: identify which speed; use √(RT/M) factor; mixture by moles.
  2. First law: path → ΔU → w → q.
  3. Adiabatic/polytropic: correct invariant.
  4. Cycle: leg table; η vs Carnot bound.

Must automate

  • Mono/dia C_v, C_p, γ
  • Isochoric/isobaric/isothermal/adiabatic quick set
  • Carnot η and refrigerator COP definitions

Traps

  • Averaging γ of a mixture linearly
  • Using °C in Carnot formula
  • Efficiency with |Q_cold| in the denominator

Drill

Daily: 1 kinetic ratio + 1 first-law/cycle NUM

03 · Medium — easy if kelvin-safe

Heat Transfer · Radiation

45s triggerSee cooling rate, Stefan, Wien → net T⁴ or λ_max T=b.

Template (write on rough)

  1. Newton cooling: θ=T−T₀; exponential fit.
  2. Stefan: kelvin; net power if enclosure given.
  3. Wien: λ_max T=b independent of Stefan power.
  4. MC: separate spectral peak from total power claims.

Must automate

  • Net Stefan numerical
  • Wien temperature from peak shift
  • e factor on power only (not on Wien b)

Traps

  • Forgetting surroundings temperature in net radiation
  • Using Wien to replace Stefan

Drill

3×/week: 1 Stefan + 1 Wien/cooling stem

Habit

Common practice system

Same system every week — builds transferable speed.

Daily

  • 20 min: 4 Thermal stems across expansion, kinetic, process, radiation — path/phase named by 15s.
  • Write sign convention once at the top of every thermo solution.
  • Redo any cycle where ΣΔU≠0 on your table.

Weekly

  • 1 full PV-cycle set with η and Carnot comparison.
  • 1 mixture C_v/γ blitz (6 questions).
  • Error log: kelvin misses, phase impossibilities, γ averaging.

Before every mock

  • Flash: process rules, Carnot, v_rms, Stefan/Wien — 6 minutes.
  • In paper: bank direct first-law and expansion asks early.
Full marks gate

100% checklist for Thermal Physics

Tick these only when true on timed practice — not when “you know the chapter”.
  • Every first-law stem starts with a path label.
  • Calorimetry always tests phase feasibility.
  • Mixture γ never mole-averaged directly.
  • Cycle efficiency uses Q_in only.
  • Carnot comparisons use kelvin temperatures.
  • Radiation uses net T⁴ when T₀ is given.
  • Wien and Stefan are applied independently when both appear.
  • Process path named before computing Q or W.
  • rms / f degrees of freedom match the gas model used.
Also study

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